OK yeah - that is one factor that may make the difference between a "test" and "real world" - The surface area of the headspace above the samples -
less surface area = less air to interact with or carry moisture.
a 3 ounce sample in a dish will go bad far more quickly than the same 3 ounce sample in a vial - with or without covers/lids - So, any testing needs to have those "caveats" noted as well..
Ideally a true test would be to purchase a dozen 1 gallon gas cans, and fill them with exactly 1 gallon each (BY WEIGHT, down to the ounce, not by volume - that way you can also weight later them to check the rate of evaporation!) , then add in your "test" parameters to each. but, obviously, with the price of gas cans these days probably not exactly a feasible test unless you have a bunch of cash you can afford to throw away like that..
Of course, if you have some suitable sealed containers that won't be affected by the gas or additives, those could work as well..
can you tell the thought to run some tests just like that have crossed my mind before? LOL!
How poor are they who have not patience. What wound did ever heal, but by degrees? - Iago (Othello Act II, Scene 3)